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Asymmetric Baeyer-Villiger Oxidations Using Biocatalysts. Development and Application of 2nd Generation of Biocatalysts

Автор:   Radka S.
мягкая обложка
288 страниц
2009 год
Издательство:   Книга по Требованию
Цена:
3212 руб
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Описание:For the transformation of achiral ketones to chiral lactones, Baeyer-Villiger monooxygenases (BVMOs) were utilized, since these enzymes exhibit wide substrate specificity and high enantioselectivity. The advantage of this approach is that BVMOs can generate several chiral centers in a single biotransformation step. Various cofactor recycling options have also been considered during this study. As a direct consequence of this research, a metabolically independent biocatalyst was developed, which performs cofactor regeneration concomitantly with the oxygenation reaction. . Such a system is very attractive for industrial applications as operational costs are dramatically reduced due to the absence for the requirement of co-factor recycling. Such lactones can serve as versatile building blocks in natural product and bioactive compound synthesis. Chiral lactones are important building blocks in organic synthesis. A broad range of useful products are accessible via enantioselective Baeyer-Villiger oxidation of simple ketones.


Orthomol Immun Junior Сила иммунитета на страже Вашего ребенка Orthomol Immun Junior Сила иммунитета на страже Вашего ребенка

2990 руб
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Real-Time Concepts for Embedded Systems

The result is that each side can take advantage of what the other can do. The software component can take advantage of special hardware features to gain performance. The hardware component can simplify module design if functionality can be achieved in software that reduces overall hardware complexity and cost. Often design flaws, in both the hardware and software, are uncovered during this close collaboration. The hardware and software co-design model reemphasizes the fundamental characteristic of embedded systems-they are application-specific. An embedded system is usually built on custom hardware and software. Therefore, using this development model is both permissible and beneficial. 1.1.7 Cross-Platform Development Another typical characteristic of embedded systems is its method of software development, called cross-platform development, for both system and application software. Software for an embedded system is developed on one platform but runs on another. In this context, the platform is the combination of hardware (such as particular type of processor), operating system, and software development tools used for further development ...»

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Деревянный конструктор "Изба" (39 деталей).
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487 руб
Раздел: Наборы


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